import re
 
s = """:VPN () :add_adtr_rule (true) :additional_products () :addr_type_indication (IPv4) :certificates () :color (black) :comments () :connectra (false) :connectra_settings () :cp_products_installed (false) :data_source (not-installed) :data_source_settings () :edges () :enforce_gtp_rate_limit (false) :firewall (not-installed) :floodgate (not-installed) :gtp_rate_limit (2048) :interfaces () :ipaddr (10.19.45.18)"""
r = r"(?s).*?(?:add_adtr_rule\s\(true\)).*?:ipaddr\s\((.*?)\)"
ip = re.findall(r, s)
print (ip)

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