#!/bin/bash
rx='^([^,]*),([^,]*),([^,]*,[^,]*,[^,]*,[^,]*,[^,]*,(shooting|judo),[^,]*,[^,]*,[^,]*,[^,]*)$'
repl='\1,\U\2\E,\3'

s='id,name,nationality,sex,date_of_birth,height,weight,sport,gold,silver,bronze,info
736041664,A Jesus Garcia,ESP,male,1969-10-17,1.72,64,athletics,0,0,0,
132041664,A Jesus Garcia,ESP,male,1969-10-17,1.72,64,shooting,0,0,0,'

sed -E "s/$rx/$repl/" <<< "$s"