fork(5) download
<?php

$headers="From: John <john@somesite.com> To: Susy <susy@mysite.com>, Steven <steven@somesite.com>, Mary <mary@mysite.com>";
preg_match_all("/<([^><]+)/", $headers, $matches);
print_r($matches[1]);
Success #stdin #stdout 0.01s 20520KB
stdin
Standard input is empty
stdout
Array
(
    [0] => john@somesite.com
    [1] => susy@mysite.com
    [2] => steven@somesite.com
    [3] => mary@mysite.com
)