<?php
$str = "MATERIALS,1,1,9999;1 4PL1 PB_Mel,,1,6,0.173,0.173,0.375,0,0.375,0,0,0,0,2,0,1,1\n".
"MATERIALS,1,1,9999;1 4PL1 PB_Mel,,1,6,0.173,0.173,0.375,0,0.375,0,0,0,0,2,0,1,1";
print preg_replace('/^(MATERIALS,(?:[^,]*,){4}\d+)(?=,)/m', "$1.001", $str); ?>
PD9waHAKJHN0ciA9ICJNQVRFUklBTFMsMSwxLDk5OTk7MSA0UEwxIFBCX01lbCwsMSw2LDAuMTczLDAuMTczLDAuMzc1LDAsMC4zNzUsMCwwLDAsMCwyLDAsMSwxXG4iLgogICAgICAgIk1BVEVSSUFMUywxLDEsOTk5OTsxIDRQTDEgUEJfTWVsLCwxLDYsMC4xNzMsMC4xNzMsMC4zNzUsMCwwLjM3NSwwLDAsMCwwLDIsMCwxLDEiOwpwcmludCBwcmVnX3JlcGxhY2UoJy9eKE1BVEVSSUFMUywoPzpbXixdKiwpezR9XGQrKSg/PSwpL20nLCAiJDEuMDAxIiwgJHN0cik7Cj8+
MATERIALS,1,1,9999;1 4PL1 PB_Mel,,1.001,6,0.173,0.173,0.375,0,0.375,0,0,0,0,2,0,1,1
MATERIALS,1,1,9999;1 4PL1 PB_Mel,,1.001,6,0.173,0.173,0.375,0,0.375,0,0,0,0,2,0,1,1