<name>kek</name><value>11</value>
<name>lol</name><value>22</value>
<name>wow</name><value>33</value>
Результат.
Array
(
[0] => Array
(
[0] => kek
[1] => 11
),
[1] => Array
(
[0] => lol
[1] => 22
),
[2] => Array
(
[0] => wow
[1] => 33
),
<?php
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