<?php
$xml = '<Sites>
<Items>
<Item>
<id>1</id>
<URL>https://m...content-available-to-author-only...e.com</URL>
<Host>mysite.com</Host>
<Folder>mysite</Folder>
<Database>mysite_app</Database>
<DBuser>mysite_app</DBuser>
<DBpassword>pass</DBpassword>
</Item>
<Item>
<id>2</id>
<URL>https://m...content-available-to-author-only...e.com</URL>
<Host>mysite.com</Host>
<Folder>mysite</Folder>
<Database>mysite_app</Database>
<DBuser>mysite_app</DBuser>
<DBpassword>pass</DBpassword>
</Item>
<Item>
<id>50</id>
<URL>https://m...content-available-to-author-only...e.com</URL>
<Host>mysite.com</Host>
<Folder>mysite</Folder>
<Database>mysite_app</Database>
<DBuser>mysite_app</DBuser>
<DBpassword>pass</DBpassword>
</Item>
<Item>
<id>100500</id>
<URL>https://m...content-available-to-author-only...e.com</URL>
<Host>mysite.com</Host>
<Folder>mysite</Folder>
<Database>mysite_app</Database>
<DBuser>mysite_app</DBuser>
<DBpassword>pass</DBpassword>
</Item>
</Items>
</Sites>
';
$doc = new DOMDocument();
$doc->loadXML($xml);
$items = $doc->getElementsByTagName('id');
echo 'Значение последнего ID: ', $items->item($items->length - 1)->nodeValue;